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Heavily fluorinated carbohydrates as enzyme substrates: oxidation of tetrafluorinated galactose by galactose oxidase
Ioannou, Avgousta; Cini, Elena; Timofte, Roxana S; Flitsch, Sabine L; Turner, Nicholas J; Linclau, Bruno
Chemical Communications. 2011;47(40):11228-11230.
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Abstract
Galactose oxidase (GOase) was shown to oxidise several C2/C3 fluorinated galactose analogues. Interestingly, the enzyme was able to distinguish between the 2,3-tetrafluorinated galactose and its epimeric glucose analogue, and this represents the first reported biotransformation of a heavily fluorinated sugar.
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Volume:
47
Issue:
40
Start page:
11228
End page:
11230
Total:
3
Pagination:
11228-11230
Digital Object Identifier:
10.1039/c1cc13956h
ISI Accession Number:
WOS:000295483800011
Related website(s):
- Related website <Go to ISI>://WOS:000295483800011
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- Times Cited: 0
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Active
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Manchester eScholar ID:
uk-ac-man-scw:150595
Created by:
Turner, Nicholas
Created:
14th January, 2012, 14:38:17
Last modified by:
Turner, Nicholas
Last modified:
14th January, 2012, 14:38:17