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Cyclic and Spirocyclic α-Tertiary Amines by Organolithium Rearrangement

Overy, Anthony Jason

[Thesis]. Manchester, UK: The University of Manchester; 2015.

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Abstract

Spirocyclic & cyclic α-tertiary amines are frequently found in naturally occurring biological and synthetic molecules. Synthetic methods which allow the concise synthesis of such molecules are of high value within organic synthesis. The application of a specific organolithium rearrangement with regards to this family of amines has developed and broadened within this thesis. Attempts to synthesis a variety of novel compounds is covered, with the aim of not only broadening the utility of organolithium reaction for the construction of this otherwise challenging class of amines, but to highlight and showcase its utility in the synthesis of the structurally complex alkaloids.

Bibliographic metadata

Type of resource:
Content type:
Administered thesis
Form of thesis:
Traditional
Type of submission:
Doctoral level ETD - final
Thesis title:
Cyclic and Spirocyclic α-Tertiary Amines by Organolithium Rearrangement
Degree type:
Master of Philosophy
Degree programme:
MPhil Chemistry
Publication date:
2015-01-07T14:41:35
Institution:
The University of Manchester
Location:
Manchester, UK
Total pages:
108
Abstract:
Spirocyclic & cyclic α-tertiary amines are frequently found in naturally occurring biological and synthetic molecules. Synthetic methods which allow the concise synthesis of such molecules are of high value within organic synthesis. The application of a specific organolithium rearrangement with regards to this family of amines has developed and broadened within this thesis. Attempts to synthesis a variety of novel compounds is covered, with the aim of not only broadening the utility of organolithium reaction for the construction of this otherwise challenging class of amines, but to highlight and showcase its utility in the synthesis of the structurally complex alkaloids.
Additional digital content not deposited electronically:
N/A
Non-digital content not deposited electronically:
N/A
Keyword(s):
Thesis main supervisor(s):
Thesis co-supervisor(s):
Degree grantor:
Language:
en

Institutional metadata

University researcher(s):
Academic department(s):

Record metadata

Manchester eScholar ID:
uk-ac-man-scw:245070
Created by:
Overy, Anthony
Created:
7th January, 2015, 14:41:36
Last modified by:
Overy, Anthony
Last modified:
17th November, 2017, 08:44:31

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