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- DOI: 10.1039/b300214d
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Aqueous micellar solutions of a triblock copolymer of ethylene oxide and 1,2-butylene oxide, B12E114B12. Scaling the viscoelasticity of fluid and gel
Kelarakis, Antonis; Yuan, Xue-Feng; Mai, Shao-Min; Yang, Yung-Wei; Booth, Colin
Phys. Chem. Chem. Phys. FIELD Full Journal Title:Physical Chemistry Chemical Physics. 2003;5(12):2628-2634.
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Full-text held externally
- DOI: 10.1039/b300214d
Abstract
Aq. solns. of triblock copolymer B12E114B12 have been characterized rheometrically over the concn. range 10-40 wt. % And at several temps. Through micellar bridging the micellar interaction is weakly attractive. A wide variety of linear viscoelastic behaviors are obsd., and it is shown that they can be superposed onto a master curve of the type developed by Trappe and Weitz (Phys. Rev. Lett., 2000, 85, 449) for conventional colloidal suspensions of weakly-attractive particles. [on SciFinder(R)]
Keyword(s)
Gels; Loss modulus; Micelles (aq. micellar solns. of a triblock copolymer of ethylene oxide and 1,2-butylene oxide, B12E114B12. scaling the viscoelasticity of fluid and gel) ; Phase diagram; Polymerization (ring-opening; Polyoxyalkylenes Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (block ; Storage modulus; Stress (yield; Viscoelasticity; Viscosity (soln. property of a triblock copolymer of ethylene oxide and 1,2-butylene oxide) ; aq. micellar solns. of a triblock copolymer of ethylene oxide and 1,2-butylene oxide, B12E114B12. scaling the viscoelasticity of fluid and gel) ; in prepn. of a triblock copolymer of ethylene oxide and 1,2-butylene oxide); soln. property of a triblock copolymer of ethylene oxide and 1,2-butylene oxide); triblock copolymer ethylene oxide butylene oxide micellar soln property
Bibliographic metadata
- CAN 139:324057 36-7 Physical Properties of Synthetic High Polymers Journal 1463-9076 written in English 107628-12-6P (1,2-Butylene oxide-oxirane block copolymer); 717909-83-6P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (triblock; aq. micellar solns. of triblock copolymer of ethylene oxide and 1,2-butylene oxide, B12E114B12. scaling the viscoelasticity of fluid and gel)